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  5.     <title>UTas ePrints - Carbon-oxygen bond formation at organopalladium centres</title>
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  13.     <meta content="Canty, A.J." name="eprints.creators_name" />
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  25. <meta content="Carbon-oxygen bond formation at organopalladium centres	
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  30. <meta content="Palladium; Organopalladium(IV); 2,2′-bipyridine; N,N,N′,N′-tetramethylethlenediamine; Catalysis; Peroxide; Crystal structure " name="eprints.keywords" />
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  33. <meta content="The reaction of PdMe2(bpy) (bpy = 2,2-bipyridine) with
  34.  diaroyl peroxides is
  35.  a complex process in which initial 
  36. oxidation of Pd(II) is followed by methyl
  37.  group exchange between an undetected
  38.  Pd(IV) intermediate and PdMe2(bpy) to give
  39.  PdMe(O2CAr)(bpy) and PdMe3(O2CAr)(bpy); the latter
  40.  Pd(IV) complex decomposes by 
  41. elimination of Me–Me to give additional 
  42. PdMe(O2CAr)(bpy) which reacts
  43.  with (ArCO2)2 to give Me–O2CAr 
  44. and Pd(O2CAr)2(bpy).
  45.  The complexes Pd(O2CPh)2(L2) 
  46. (L2=bpy, N,N,N′,N′-tetramethylethylyenediamine)
  47.  have been characterised by X-ray diffraction." name="eprints.abstract" />
  48. <meta content="2001" name="eprints.date" />
  49. <meta content="published" name="eprints.date_type" />
  50. <meta content="Inorganic Chemistry Communications" name="eprints.publication" />
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  57. <meta content="[IJ T. Yoneyamu. R.H. Crabtree. J. Molec. Cal. (108) (1996) .15. [2J C. Sinha. D. Bandyopadhyay. A. Chakravorty. Inorg. Chcm. 27 (1988) 1173. P] I).L. Alstcrs. H.T. Teunissen. J. Boersma. AL. Spck. G. van Koteu. Organomctallics 12 (1993) 4691. [4) J-M. vnn. J. Boersma, G. van Koren. Organometallics 15 (19961
  58. 4.166.
  59. [5J P.L. Alsrcrs. J. Boersma, G. van Koren. Organometnlhcs 12 (199.1) 1629.
  60. [6] K. Kamaraj. D. Bandyopadhyay, Orgauomctalhcs 18 (1999) 438.
  61. (7) P. wadhwani. D. Bandyopadhyay. Organometallics 19 (2000)
  62. 44.15. Itll AJ. Canty. n. Jin. B.W. Skcltl1n, AH. Whitc, Inorg. Chern. 37 ([998) .1975.
  63. [9J B. Milani. E. Alessio, G. Mestroni. A. Sornmazzi. F. Garbassi. E. Zangrundo. N. Bresctani-Pahor. L. Randaecio. J. Chern. Dalton Trans. S(1C. (19941 19()J.
  64. [IOJ B.A Markics. AJ. Canty. J. Boersma. G. van Koren. Organometallics
  65. IJ (1994) 2053.
  66. [II] AJ. Canty. in: 1:::&quot;1. Negishi (Ed.). Handbook or Organopulladnuu
  67. Chemistry for Organic Synthesis, Wiley. New York, 20(11 (Chapter 11.4, in press).
  68. [[21 P.K. Byers. AJ. Canty. n.w. Skelton. A.H. White, Organometallies
  69. 9 (1990) 826. (13] A.J. Canty. P.R. Trail\, B.W. Skelton, A.H. White. J. Organomet. Chern. 433 (1992) 21J." name="eprints.referencetext" />
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  73. <meta content="Carbon-oxygen bond formation at organopalladium centres	
  74. " name="DC.title" />
  75. <meta content="Canty, A.J." name="DC.creator" />
  76. <meta content="Done, M.C." name="DC.creator" />
  77. <meta content="Skelton, B.W." name="DC.creator" />
  78. <meta content="White, A.H." name="DC.creator" />
  79. <meta content="259901 Organometallic Chemistry" name="DC.subject" />
  80. <meta content="The reaction of PdMe2(bpy) (bpy = 2,2-bipyridine) with
  81.  diaroyl peroxides is
  82.  a complex process in which initial 
  83. oxidation of Pd(II) is followed by methyl
  84.  group exchange between an undetected
  85.  Pd(IV) intermediate and PdMe2(bpy) to give
  86.  PdMe(O2CAr)(bpy) and PdMe3(O2CAr)(bpy); the latter
  87.  Pd(IV) complex decomposes by 
  88. elimination of Me–Me to give additional 
  89. PdMe(O2CAr)(bpy) which reacts
  90.  with (ArCO2)2 to give Me–O2CAr 
  91. and Pd(O2CAr)2(bpy).
  92.  The complexes Pd(O2CPh)2(L2) 
  93. (L2=bpy, N,N,N′,N′-tetramethylethylyenediamine)
  94.  have been characterised by X-ray diffraction." name="DC.description" />
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  208.     <h1 class="ep_tm_pagetitle">Carbon-oxygen bond formation at organopalladium centres</h1>
  209.     <p style="margin-bottom: 1em" class="not_ep_block"><span class="person_name">Canty, A.J.</span> and <span class="person_name">Done, M.C.</span> and <span class="person_name">Skelton, B.W.</span> and <span class="person_name">White, A.H.</span> (2001) <xhtml:em>Carbon-oxygen bond formation at organopalladium centres.</xhtml:em> Inorganic Chemistry Communications, 4 . pp. 648-650. ISSN 1387-7003</p><p style="margin-bottom: 1em" class="not_ep_block"></p><table style="margin-bottom: 1em" class="not_ep_block"><tr><td valign="top" style="text-align:center"><a href="http://eprints.utas.edu.au/2796/1/ICC2001_2C_648.pdf"><img alt="[img]" src="http://eprints.utas.edu.au/style/images/fileicons/application_pdf.png" border="0" class="ep_doc_icon" /></a></td><td valign="top"><a href="http://eprints.utas.edu.au/2796/1/ICC2001_2C_648.pdf"><span class="ep_document_citation">PDF</span></a> - Full text restricted - Requires a PDF viewer<br />96Kb</td><td><form method="get" accept-charset="utf-8" action="http://eprints.utas.edu.au/cgi/request_doc"><input value="3826" name="docid" accept-charset="utf-8" type="hidden" /><div class=""><input value="Request a copy" name="_action_null" class="ep_form_action_button" onclick="return EPJS_button_pushed( '_action_null' )" type="submit" /> </div></form></td></tr></table><p style="margin-bottom: 1em" class="not_ep_block">Official URL: <a href="http://dx.doi.org/10.1016/S1387-7003(01)00296-9">http://dx.doi.org/10.1016/S1387-7003(01)00296-9</a></p><div class="not_ep_block"><h2>Abstract</h2><p style="padding-bottom: 16px; text-align: left; margin: 1em auto 0em auto">The reaction of PdMe2(bpy) (bpy = 2,2-bipyridine) with&#13;
  210.  diaroyl peroxides is&#13;
  211.  a complex process in which initial &#13;
  212. oxidation of Pd(II) is followed by methyl&#13;
  213.  group exchange between an undetected&#13;
  214.  Pd(IV) intermediate and PdMe2(bpy) to give&#13;
  215.  PdMe(O2CAr)(bpy) and PdMe3(O2CAr)(bpy); the latter&#13;
  216.  Pd(IV) complex decomposes by &#13;
  217. elimination of Me–Me to give additional &#13;
  218. PdMe(O2CAr)(bpy) which reacts&#13;
  219.  with (ArCO2)2 to give Me–O2CAr &#13;
  220. and Pd(O2CAr)2(bpy).&#13;
  221.  The complexes Pd(O2CPh)2(L2) &#13;
  222. (L2=bpy, N,N,N′,N′-tetramethylethylyenediamine)&#13;
  223.  have been characterised by X-ray diffraction.</p></div><table style="margin-bottom: 1em" border="0" cellpadding="3" class="not_ep_block"><tr><th valign="top" class="ep_row">Item Type:</th><td valign="top" class="ep_row">Article</td></tr><tr><th valign="top" class="ep_row">Additional Information:</th><td valign="top" class="ep_row">The definitive version is available at http://www.sciencedirect.com&#13;
  224. </td></tr><tr><th valign="top" class="ep_row">Keywords:</th><td valign="top" class="ep_row">Palladium; Organopalladium(IV); 2,2′-bipyridine; N,N,N′,N′-tetramethylethlenediamine; Catalysis; Peroxide; Crystal structure </td></tr><tr><th valign="top" class="ep_row">Subjects:</th><td valign="top" class="ep_row"><a href="http://eprints.utas.edu.au/view/subjects/259901.html">250000 Chemical Sciences &gt; 259900 Other Chemical Sciences &gt; 259901 Organometallic Chemistry</a></td></tr><tr><th valign="top" class="ep_row">Collections:</th><td valign="top" class="ep_row">UNSPECIFIED</td></tr><tr><th valign="top" class="ep_row">ID Code:</th><td valign="top" class="ep_row">2796</td></tr><tr><th valign="top" class="ep_row">Deposited By:</th><td valign="top" class="ep_row"><span class="ep_name_citation"><span class="person_name">Prof Allan J Canty</span></span></td></tr><tr><th valign="top" class="ep_row">Deposited On:</th><td valign="top" class="ep_row">04 Jan 2008 10:47</td></tr><tr><th valign="top" class="ep_row">Last Modified:</th><td valign="top" class="ep_row">18 Jan 2008 13:22</td></tr><tr><th valign="top" class="ep_row">ePrint Statistics:</th><td valign="top" class="ep_row"><a target="ePrintStats" href="/es/index.php?action=show_detail_eprint;id=2796;">View statistics for this ePrint</a></td></tr></table><p align="right">Repository Staff Only: <a href="http://eprints.utas.edu.au/cgi/users/home?screen=EPrint::View&amp;eprintid=2796">item control page</a></p>
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